George Moriarty (1885)
Double Duty Radcliffe (1902)
Satchel Paige (1906)
Billy Herman (1909)
Sammy White (1927)
John Gordon (1940)
Bill Melton (1945)
Tommy Moore (1948)
Len Barker (1955)
Dan Gladden (1957)
Glenn Hoffman (1958)
Tim Teufel (1958)
Dave Burba (1966)
Jeff Shaw (1966)
Chuck Knoblauch (1968)
Matt Mantei (1973)
Cory Provus (1978)
John Buck (1980)
Brandon McCarthy (1983)
Ted “Double Duty” Radcliffe played in the Negro Leagues for many years. He got his nickname because he would sometimes catch one game of a doubleheader and pitch the other. He played professionally until 1954, when he retired at age 52. He is the oldest player to ever appear in a professional baseball game, throwing one pitch for the Schaumberg Flyers of the Northern League in 1999 when he was 96. I'm no expert on the Negro Leagues, but it seems to me that he should be in the Hall of Fame.
John Gordon was a radio broadcaster for the Twins from 1987 through 2011.
Tommy Moore was drafted by Minnesota in the twenty-eighth round in 1966, but did not sign.
Cory Provus has been a radio broadcaster for the Twins since 2012.